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Mustard Gas as a antineoplastic agent | UK US Essays
  • April 11th, 2016

Mustard Gas as a antineoplastic agent

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Essay: Researchers at Yale were the first to harness the reactivity of mustard gas by replacing the bivalent sulfur atom with a trivalent nitrogen atom. Discuss how the reactivity of the resulting nitrogen mustards can be controlled to give a perfectly-tuned antineoplastic agent. You may draw and annotate structures to help explain your answer. **One mechanism to depict how an archetypal nitrogen mustard reacts with DNA should be given.** The nucleophilic group of DNA that typically reacts with the mustards is the N7 position of guanine; for simplicity, refer to this as “DNA-NH2”.

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